I would like to know how I can get access to the underlying database powering the site safeharbor
This lists all the private companies who have agreed to comply with the Safe Harbor protocol for EU data protection.
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I checked out the webpage. There is a 'Export to Excel' link on the page. I tried it. It downloads a file called 'OrganizationList.xls'. But you cannot open it in Excel. I checked the contents of the file and it is an HTML table. To view the file, change the file suffix to '.html'.
As far as extracting the data, I would use a convert HTML table to CSV tool. Below is one site that I tried with this file and it appeared to do a correct conversion: